Donaldsonville High School Principals
| L.C. Ferrell | 1885-1889 | |
| G.C. Cole | 1889-1890 | |
| A. W. Meadows | 1890-1892 | |
| M. Knobloch | 1892-1893 | |
| Wm. J. Gahan | 1893-1895 | |
| R.N. Sims | 1895-1898 | |
| J.O. Taylor | 1989-1902 | |
| J.L. Rusca | 1902-1909 | |
| Arnold Pearce | 1909-1910 | |
| J.H. Dupy | 1910-1911 | |
| H.B. Messick | 1911-1912 | |
| A.J. Dupy | 1912 | |
| R.S. Vickers | 1912-1914 | |
| W.H. Miller | 1914-1915 | |
| R.S. Vickers | 1915-1919 | |
| B.C. Alwes | 1919-1951 | |
| C.C. Goette | 1951-1965 | |
| Keith Falcon | 1965-1973 | |
| John Oubre | 1973-1977 | |
| Violet Marchand | 1977-1980 | |
| Emile Chiquet | 1981-1993 | |
| Gerald Alexander | 1993-1998 | |
| Ronald Rabalais | 1999-2006 | |
| Gwen Boudreaux | 2006 - Present |